Scalable Synthesis of (−)-Thapsigargin

[Image: see text] Total syntheses of the complex, highly oxygenated sesquiterpenes thapsigargin (1) and nortrilobolide (2) are presented. Access to analogues of these promising bioactive natural products has been limited to tedious isolation and semisynthetic efforts. Elegant prior total syntheses d...

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Bibliografiske detaljer
Udgivet i:ACS Cent Sci
Main Authors: Chu, Hang, Smith, Joel M., Felding, Jakob, Baran, Phil S.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2016
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5269647/
https://ncbi.nlm.nih.gov/pubmed/28149952
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00313
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