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Studies of stereocontrolled allylation reactions for the total synthesis of phorboxazole A
A highly convergent total synthesis of the potent anticancer agent (+)-phorboxazole A (1) is accomplished. Four components (3–6) are assembled with considerations for control of absolute and relative stereochemistry. Iterative asymmetric allylation methodology addresses key stereochemical features i...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2004
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC514434/ https://ncbi.nlm.nih.gov/pubmed/15277662 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0402477101 |
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