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Stereocontrolled total synthesis of (+)-vincristine

An efficient total synthesis of (+)-vincristine has been accomplished through a stereoselective coupling of demethylvindoline and the eleven-membered carbomethoxyverbanamine presursor. Demethylvindoline was prepared by oxidation of 17-hydroxy-11-methoxytabersonine, followed by regioselective acetyla...

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Autors principals: Kuboyama, Takeshi, Yokoshima, Satoshi, Tokuyama, Hidetoshi, Fukuyama, Tohru
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2004
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC514417/
https://ncbi.nlm.nih.gov/pubmed/15141084
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401323101
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