Φορτώνει......
Total synthesis of (–)-spinosyn A
A convergent, highly stereoselective total synthesis of (–)-spinosyn A (1) is described. Key features of the synthesis include the transannular Diels–Alder reaction of macrocyclic pentaene 11 and the transannular Morita–Baylis–Hillman cyclization of 12 that generates tetracycle 26. The total synthes...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
National Academy of Sciences
2004
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC514415/ https://ncbi.nlm.nih.gov/pubmed/15173590 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401247101 |
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