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Stereocontrolled Total Synthesis of (−)‐Stemaphylline
Homologation of readily available α‐boryl pyrrolidines with metal carbenoids is especially challenging even when good leaving groups (Cl(−)) are employed. By performing a solvent switch from Et(2)O to CHCl(3), efficient 1,2‐metalate rearrangement of the intermediate boronate occurs with both halide...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5484348/ https://ncbi.nlm.nih.gov/pubmed/28097799 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611273 |
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