Asymmetric Synthesis of Tertiary Alcohols and Thiols via Nonstabilized Tertiary α‐Oxy‐ and α‐Thio‐Substituted Organolithium Species

Nonstabilized α‐O‐substituted tertiary organolithium species are difficult to generate, and the α‐S‐substituted analogues are configurationally unstable. We now report that they can both be generated easily and trapped with a range of electrophiles with high enantioselectivity, providing ready acces...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Pulis, Alexander P., Varela, Ana, Citti, Cinzia, Songara, Pradip, Leonori, Daniele, Aggarwal, Varinder K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5601220/
https://ncbi.nlm.nih.gov/pubmed/28783238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706722
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