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Toward the synthesis of the carbacylic ansa antibiotic kendomycin
The convergent synthesis of a benzofuran analog of the carbacyclic ansa compound kendomycin has been achieved by assembling three major fragments by means of epoxide opening and directed ortho lithiation. The crucial tetrahydropyran ring was formed by a highly stereoselective cationic cyclization. A...
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| Autores principales: | , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
National Academy of Sciences
2004
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC514420/ https://ncbi.nlm.nih.gov/pubmed/15277689 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401503101 |
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