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Toward the synthesis of the carbacylic ansa antibiotic kendomycin
The convergent synthesis of a benzofuran analog of the carbacyclic ansa compound kendomycin has been achieved by assembling three major fragments by means of epoxide opening and directed ortho lithiation. The crucial tetrahydropyran ring was formed by a highly stereoselective cationic cyclization. A...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2004
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC514420/ https://ncbi.nlm.nih.gov/pubmed/15277689 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0401503101 |
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