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The hexadehydro-Diels-Alder (HDDA) cycloisomerization reaction proceeds by a stepwise mechanism
We report here experiments showing that the hexadehydro-Diels–Alder (HDDA) cycloisomerization reaction proceeds in a stepwise manner—i.e., via a diradical intermediate. Judicious use of substituent effects was decisive. We prepared: (i) a series of triyne HDDA substrates that differed only in the gr...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5136458/ https://ncbi.nlm.nih.gov/pubmed/27266843 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03786 |
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