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The hexadehydro-Diels-Alder reaction: Benzyne generation via cycloisomerization of tethered triynes
The hexadehydro-Diels-Alder (HDDA) reaction is the thermal cyclization of an alkyne and a 1,3-diyne to generate a benzyne intermediate. This is then rapidly trapped, in situ, by a variety of species to yield highly functionalized benzenoid products. In contrast to nearly all other methods of aryne g...
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| Publicado en: | Chem Rev |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2021
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8008985/ https://ncbi.nlm.nih.gov/pubmed/33492939 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemrev.0c00825 |
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