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A multicomponent approach for the preparation of homoallylic alcohols
Here we report the in situ generation of transient allylic boronic species, by reacting TMSCHN(2) and E-vinyl boronic acids, followed by their subsequent trapping with aldehydes as electrophiles to yield homoallylic alcohols. This metal-free reaction was initially discovered by the use of a flow che...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5134730/ https://ncbi.nlm.nih.gov/pubmed/28042466 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02581a |
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