A Versatile Room-Temperature Route to Di- and Trisubstituted Allenes Using Flow-Generated Diazo Compounds**

A copper-catalyzed coupling reaction between flow-generated unstabilized diazo compounds and terminal alkynes provides di- and trisubstituted allenes. This extremely mild and rapid transformation is highly tolerant of several functional groups.

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Poh, Jian-Siang, Tran, Duc N, Battilocchio, Claudio, Hawkins, Joel M, Ley, Steven V
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4515080/
https://ncbi.nlm.nih.gov/pubmed/26013774
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201501538
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