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Unveiling the role of boroxines in metal-free carbon–carbon homologations using diazo compounds and boronic acids
By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon–carbon homologation of aryl and vinyl boroxines using TMSCHN(2), giving access to TMS...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5859889/ https://ncbi.nlm.nih.gov/pubmed/29619197 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02264f |
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