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Catalytic, Diastereoselective 1,2-Difluorination of Alkenes
We describe a direct, catalytic approach to the 1,2-difluorination of alkenes. The method utilizes a nucleophilic fluoride source and an oxidant in conjunction with an aryl iodide catalyst and is applicable to alkenes with all types of substitution patterns. In general, the vicinal difluoride produc...
Guardat en:
| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5097459/ https://ncbi.nlm.nih.gov/pubmed/27046019 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02391 |
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