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An organometallic complex formed by an unconventional radical SAM enzyme
Pyrococcus horikoshii Dph2 (PhDph2) is an unusual radical SAM enzyme involved in the first step of diphthamide biosynthesis. It catalyzes the reaction by cleaving S-adenosylmethionine (SAM) to generate a 3-amino-3-carboxy propyl (ACP) radical. To probe the reaction mechanism, we synthesized a SAM an...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5068486/ https://ncbi.nlm.nih.gov/pubmed/27465315 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04155 |
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