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Radical SAM Catalysis via an Organometallic Intermediate with an Fe–[5′-C]-Deoxyadenosyl Bond
Radical SAM enzymes use a [4Fe-4S] cluster to cleave S-adenosylmethionine (SAM) to initiate diverse radical reactions. These are thought to involve the 5′-deoxyadenosyl radical intermediate, which has not yet been detected. Here we rapid freeze-quench trap a catalytically competent intermediate in t...
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| Publicado no: | Science |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4929858/ https://ncbi.nlm.nih.gov/pubmed/27174986 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf5327 |
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