Monovalent Cation Activation of the Radical SAM Enzyme Pyruvate Formate-Lyase Activating Enzyme

[Image: see text] Pyruvate formate-lyase activating enzyme (PFL-AE) is a radical S-adenosyl-l-methionine (SAM) enzyme that installs a catalytically essential glycyl radical on pyruvate formate-lyase. We show that PFL-AE binds a catalytically essential monovalent cation at its active site, yet anothe...

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Publicat a:J Am Chem Soc
Autors principals: Shisler, Krista A., Hutcheson, Rachel U., Horitani, Masaki, Duschene, Kaitlin S., Crain, Adam V., Byer, Amanda S., Shepard, Eric M., Rasmussen, Ashley, Yang, Jian, Broderick, William E., Vey, Jessica L., Drennan, Catherine L., Hoffman, Brian M., Broderick, Joan B.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5579537/
https://ncbi.nlm.nih.gov/pubmed/28768413
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b04883
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