Reversal of a Single Base‐Pair Step Controls Guanine Photo‐Oxidation by an Intercalating Ruthenium(II) Dipyridophenazine Complex

Small changes in DNA sequence can often have major biological effects. Here the rates and yields of guanine photo‐oxidation by Λ‐[Ru(TAP)(2)(dppz)](2+) have been compared in 5′‐{CCGGATCCGG}(2) and 5′‐{CCGGTACCGG}(2) using pico/nanosecond transient visible and time‐resolved IR (TRIR) spectroscopy. Th...

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Udgivet i:Angew Chem Int Ed Engl
Main Authors: Keane, Páraic M., Poynton, Fergus E., Hall, James P., Sazanovich, Igor V., Towrie, Michael, Gunnlaugsson, Thorfinnur, Quinn, Susan J., Cardin, Christine J., Kelly, John M.
Format: Artigo
Sprog:Inglês
Udgivet: WILEY‐VCH Verlag 2015
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4985698/
https://ncbi.nlm.nih.gov/pubmed/26096623
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201502608
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