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Direct observation by time-resolved infrared spectroscopy of the bright and the dark excited states of the [Ru(phen)(2)(dppz)](2+) light-switch compound in solution and when bound to DNA
The [Ru(phen)(2)(dppz)](2+) complex (1) is non-emissive in water but is highly luminescent in organic solvents or when bound to DNA, making it a useful probe for DNA binding. To date, a complete mechanistic explanation for this “light-switch” effect is still lacking. With this in mind we have undert...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6005197/ https://ncbi.nlm.nih.gov/pubmed/29997799 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04514b |
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