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Reversal of a Single Base‐Pair Step Controls Guanine Photo‐Oxidation by an Intercalating Ruthenium(II) Dipyridophenazine Complex
Small changes in DNA sequence can often have major biological effects. Here the rates and yields of guanine photo‐oxidation by Λ‐[Ru(TAP)(2)(dppz)](2+) have been compared in 5′‐{CCGGATCCGG}(2) and 5′‐{CCGGTACCGG}(2) using pico/nanosecond transient visible and time‐resolved IR (TRIR) spectroscopy. Th...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
WILEY‐VCH Verlag
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4985698/ https://ncbi.nlm.nih.gov/pubmed/26096623 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201502608 |
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