Lataa...
Total Synthesis of Cryptocaryol A via Enantioselective Iridium Catalyzed Alcohol C-H Allylation()
The polyketide natural product Cryptocaryol A is prepared in 8 steps via iridium catalyzed enantioselective diol double C-H allylation, which directly generates an acetate-based triketide stereodiad. In 4 previously reported total syntheses, 17-28 steps were required. [Image: see text]
Tallennettuna:
| Julkaisussa: | Angew Chem Int Ed Engl |
|---|---|
| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2016
|
| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4834877/ https://ncbi.nlm.nih.gov/pubmed/27079820 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600591 |
| Tagit: |
Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!
|