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Total Synthesis of Cryptocaryol A via Enantioselective Iridium Catalyzed Alcohol C-H Allylation()
The polyketide natural product Cryptocaryol A is prepared in 8 steps via iridium catalyzed enantioselective diol double C-H allylation, which directly generates an acetate-based triketide stereodiad. In 4 previously reported total syntheses, 17-28 steps were required. [Image: see text]
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4834877/ https://ncbi.nlm.nih.gov/pubmed/27079820 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600591 |
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