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Enantioselective Iridium Catalyzed Phthalide Formation via Internal Redox Allylation of Phthalaldehydes()
Enantioselective phthalide synthesis is achieved through internal redox allylation of o-phthalaldehydes. Oxidative esterification is balanced by reductive carbonyl addition to achieve an overall redox neutral process. Using this method, formal syntheses of ent-spirolaxine methyl ether and CJ-12,954...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5777894/ https://ncbi.nlm.nih.gov/pubmed/29240280 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201712015 |
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