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Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp(3))–H bonds

The first nickel catalyzed deprotonative cross coupling between C(sp(3))–H bonds and aryl chlorides is reported, allowing the challenging arylation of benzylimines in the absence of directing group or stoichiometric metal activation. This methodology represents a convenient access to the (diarylmeth...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Fernández-Salas, José A., Marelli, Enrico, Nolan, Steven P.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4786957/
https://ncbi.nlm.nih.gov/pubmed/27019690
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01589h
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