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Cobalt catalyzed sp(3) C–H amination utilizing aryl azides
A dinuclear Co(ii) complex supported by a modular, tunable redox-active ligand system is capable of selective C–H amination to form indolines from aryl azides in good yields at low (1 mol%) catalyst loading. The reaction is tolerant of medicinally relevant heterocycles, such as pyridine and indole,...
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| Udgivet i: | Chem Sci |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5802275/ https://ncbi.nlm.nih.gov/pubmed/29435216 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01162k |
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