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Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp(3))–H bonds

The first nickel catalyzed deprotonative cross coupling between C(sp(3))–H bonds and aryl chlorides is reported, allowing the challenging arylation of benzylimines in the absence of directing group or stoichiometric metal activation. This methodology represents a convenient access to the (diarylmeth...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Fernández-Salas, José A., Marelli, Enrico, Nolan, Steven P.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4786957/
https://ncbi.nlm.nih.gov/pubmed/27019690
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01589h
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