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Photo-induced copper-catalyzed alkynylation and amination of remote unactivated C(sp(3))-H bonds
A method for remote radical C–H alkynylation and amination of diverse aliphatic alcohols has been developed. The reaction features a copper nucleophile complex formed in situ as a photocatalyst, which reduces the silicon-tethered aliphatic iodide to an alkyl radical to initiate 1,n-hydrogen atom tra...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
The Royal Society of Chemistry
2021
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179574/ https://ncbi.nlm.nih.gov/pubmed/34163735 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05883a |
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