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Redox-Neutral Copper (II) Carboxylate Catalyzed α-Alkynylation of Amines()
A new strategy for iminium ion isomerization was applied to the direct, redox-neutral α-alkynylation of amines. Cu(II) 2-ethylhexanoate was identified as the optimal catalyst for this three-component coupling reaction of secondary amines, aldehydes and alkynes.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3774004/ https://ncbi.nlm.nih.gov/pubmed/23440869 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201300021 |
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