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Catalytic asymmetric formal synthesis of beraprost

The first catalytic asymmetric synthesis of the key intermediate for beraprost has been achieved through an enantioselective intramolecular oxa-Michael reaction of an α,β-unsaturated amide mediated by a newly developed benzothiadiazine catalyst. The Weinreb amide moiety and bromo substituent of the...

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Bibliografske podrobnosti
izdano v:Beilstein J Org Chem
Main Authors: Kobayashi, Yusuke, Kuramoto, Ryuta, Takemoto, Yoshiji
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4685892/
https://ncbi.nlm.nih.gov/pubmed/26734111
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.285
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