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Catalytic Asymmetric Formal Total Synthesis of (−)-Triptophenolide and (+)-Triptolide
ABSTRACT: Catalytic asymmetric formal synthesis of (−)-Triptophenolide and (+)-Triptolide have been achieved. Key reaction involves Palladium catalyzed asymmetric conjugate addition of aryl boronic acid to 3-methyl cyclohexe-1-none to form quaternary carbon. Claisen rearrangement and subsequent aldo...
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| Udgivet i: | Nat Prod Bioprospect |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Springer Berlin Heidelberg
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5385656/ https://ncbi.nlm.nih.gov/pubmed/27095015 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13659-016-0100-z |
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