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A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B
[Image: see text] A concise asymmetric, formal synthesis of (+)-hamigeran B is reported. A Pd-catalyzed, decarboxylative allylic alkylation, employing a trifluoromethylated derivative of t-BuPHOX, is utilized as the enantioselective step to form the critical quaternary carbon center in excellent yie...
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| Glavni autori: | , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3045637/ https://ncbi.nlm.nih.gov/pubmed/21271716 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol102669z |
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