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Engineering a dirhodium artificial metalloenzyme for selective olefin cyclopropanation

Artificial metalloenzymes (ArMs) formed by incorporating synthetic metal catalysts into protein scaffolds have the potential to impart to chemical reactions selectivity that would be difficult to achieve using metal catalysts alone. In this work, we covalently link an alkyne-substituted dirhodium ca...

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Библиографические подробности
Опубликовано в: :Nat Commun
Главные авторы: Srivastava, Poonam, Yang, Hao, Ellis-Guardiola, Ken, Lewis, Jared C.
Формат: Artigo
Язык:Inglês
Опубликовано: Nature Pub. Group 2015
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC4525152/
https://ncbi.nlm.nih.gov/pubmed/26206238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8789
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