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Manganese terpyridine artificial metalloenzymes for benzylic oxygenation and olefin epoxidation
New catalysts for non-directed hydrocarbon functionalization have great potential in organic synthesis. We hypothesized that incorporating a Mn-terpyridine cofactor into a protein scaffold would lead to artificial metalloenzymes (ArMs) in which the selectivity of the Mn cofactor could be controlled...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4041119/ https://ncbi.nlm.nih.gov/pubmed/24904188 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2014.03.008 |
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