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Engineering a dirhodium artificial metalloenzyme for selective olefin cyclopropanation
Artificial metalloenzymes (ArMs) formed by incorporating synthetic metal catalysts into protein scaffolds have the potential to impart to chemical reactions selectivity that would be difficult to achieve using metal catalysts alone. In this work, we covalently link an alkyne-substituted dirhodium ca...
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| Udgivet i: | Nat Commun |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Nature Pub. Group
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4525152/ https://ncbi.nlm.nih.gov/pubmed/26206238 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8789 |
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