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A Triple Mutant in the Ω-loop of TEM-1 β-Lactamase Changes the Substrate Profile via a Large Conformational Change and an Altered General Base for Catalysis

β-Lactamases are bacterial enzymes that hydrolyze β-lactam antibiotics. TEM-1 is a prevalent plasmid-encoded β-lactamase in Gram-negative bacteria that efficiently catalyzes the hydrolysis of penicillins and early cephalosporins but not oxyimino-cephalosporins. A previous random mutagenesis study id...

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Foilsithe in:J Biol Chem
Main Authors: Stojanoski, Vlatko, Chow, Dar-Chone, Hu, Liya, Sankaran, Banumathi, Gilbert, Hiram F., Prasad, B. V. Venkataram, Palzkill, Timothy
Formáid: Artigo
Teanga:Inglês
Foilsithe: American Society for Biochemistry and Molecular Biology 2015
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4400348/
https://ncbi.nlm.nih.gov/pubmed/25713062
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M114.633438
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