Wird geladen...
Identification of a Key Catalytic Intermediate Demonstrates that Nitrogenase is Activated by the Reversible Exchange of N(2) for H(2)
Freeze-quenching nitrogenase during turnover with N(2) traps an S = ½ intermediate that was shown by ENDOR and EPR spectroscopy to contain N(2) or a reduction product bound to the active-site molybdenum-iron cofactor (FeMo-co). To identify this intermediate (termed here EG), we turned to a quench-cr...
Gespeichert in:
| Veröffentlicht in: | J Am Chem Soc |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
|
| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4374740/ https://ncbi.nlm.nih.gov/pubmed/25741750 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00103 |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|