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Connecting nitrogenase intermediates with the kinetic scheme for N(2) reduction by a relaxation protocol and identification of the N(2) binding state

A major obstacle to understanding the reduction of N(2) to NH(3) by nitrogenase has been the impossibility of synchronizing electron delivery to the MoFe protein for generation of specific enzymatic intermediates. When an intermediate is trapped without synchronous electron delivery, the number of e...

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Detalhes bibliográficos
Main Authors: Lukoyanov, Dmitriy, Barney, Brett M., Dean, Dennis R., Seefeldt, Lance C., Hoffman, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1785236/
https://ncbi.nlm.nih.gov/pubmed/17251348
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0610975104
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