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Unification of reaction pathway and kinetic scheme for N(2) reduction catalyzed by nitrogenase

Nitrogenase catalyzes the reduction of N(2) and protons to yield two NH(3) and one H(2). Substrate binding occurs at a complex organo-metallocluster called FeMo-cofactor (FeMo-co). Each catalytic cycle involves the sequential delivery of eight electrons/protons to this cluster, and this process has...

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Detalhes bibliográficos
Main Authors: Lukoyanov, Dmitriy, Yang, Zhi-Yong, Barney, Brett M., Dean, Dennis R., Seefeldt, Lance C., Hoffman, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3326493/
https://ncbi.nlm.nih.gov/pubmed/22460797
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1202197109
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