Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways

[Image: see text] Addition of anionic donors to the manganese(V)–oxo corrolazine complex Mn(V)(O)(TBP(8)Cz) has a dramatic influence on oxygen-atom transfer (OAT) reactivity with thioether substrates. The six-coordinate anionic [Mn(V)(O)(TBP(8)Cz)(X)](−) complexes (X = F(–), N(3)(–), OCN(–)) exhibit...

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Detalhes bibliográficos
Main Authors: Neu, Heather M., Yang, Tzuhsiung, Baglia, Regina A., Yosca, Timothy H., Green, Michael T., Quesne, Matthew G., de Visser, Sam P., Goldberg, David P.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4183610/
https://ncbi.nlm.nih.gov/pubmed/25238495
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja507177h
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