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Direct nitration and azidation of aliphatic carbons by an iron-dependent halogenase
Iron-dependent halogenases employ cis-halo-Fe(IV)-oxo (haloferryl) complexes to functionalize unactivated aliphatic carbon centers, a capability elusive to synthetic chemists. Halogenation requires (1) coordination of a halide anion (Cl(−) or Br(−)) to the enzyme's Fe(II) cofactor; (2) coupled...
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| Main Authors: | , , , , , |
|---|---|
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4076429/ https://ncbi.nlm.nih.gov/pubmed/24463698 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchembio.1438 |
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