Elucidation of the iron(IV)–oxo intermediate in the non-haem iron halogenase SyrB2

Mononuclear non-haem iron (NHFe) enzymes catalyse a wide variety of oxidative reactions including halogenation, hydroxylation, ring closure, desaturation, and aromatic ring cleavage. These are highly important for mammalian somatic processes such as phenylalanine metabolism, production of neurotrans...

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Main Authors: Wong, Shaun D., Srnec, Martin, Matthews, Megan L., Liu, Lei V., Kwak, Yeonju, Park, Kiyoung, Bell, Caleb B., Alp, E. Ercan, Zhao, Jiyong, Yoda, Yoshitaka, Kitao, Shinji, Seto, Makoto, Krebs, Carsten, Bollinger, J. Martin, Solomon, Edward I.
Format: Artigo
Jezik:Inglês
Izdano: 2013
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Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4123442/
https://ncbi.nlm.nih.gov/pubmed/23868262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature12304
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