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Substrate-Triggered Formation and Remarkable Stability of the C-H-Cleaving Chloroferryl Intermediate in the Aliphatic Halogenase, SyrB2
Aliphatic halogenases activate O(2), cleave α-ketoglutarate (αKG) to CO(2) and succinate, and form haloferryl [X-Fe(IV)=O; X = Cl, Br] complexes that cleave aliphatic C-H bonds to install halogens during the biosynthesis of natural products by non-ribosomal peptide synthetases (NRPSs). For the relat...
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| Glavni autori: | , , , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2009
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2684568/ https://ncbi.nlm.nih.gov/pubmed/19245217 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi900109z |
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