Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2)

The electronic structures of transition metal complexes of NO are controlled by the stereochemistry about the metal atom (stereochemical control of valence). The six-coordinate complex, trans-[CoNO(NCS)-(C(6)H(4) [As(CH(3))(2)](2))(2)](+), consists of [Co(III)-(N=O(-))](2+) (angle(Co-N-O) = 135°), w...

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Detalhes bibliográficos

Publicado no:	Proc Natl Acad Sci U S A
Principais autores:	Enemark, John H., Feltham, Robert D.
Formato:	Artigo
Idioma:	Inglês
Publicado em:	National Academy of Sciences 1972
Assuntos:	Physical Sciences: Chemistry
Acesso em linha:	https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389815/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592038/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.69.12.3534
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