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Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2)

The electronic structures of transition metal complexes of NO are controlled by the stereochemistry about the metal atom (stereochemical control of valence). The six-coordinate complex, trans-[CoNO(NCS)-(C(6)H(4) [As(CH(3))(2)](2))(2)](+), consists of [Co(III)-(N=O(-))](2+) (angle(Co-N-O) = 135°), w...

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Bibliografski detalji
Izdano u:Proc Natl Acad Sci U S A
Glavni autori: Enemark, John H., Feltham, Robert D.
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 1972
Teme:
Online pristup:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389815/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592038/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.69.12.3534
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