Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2)
The electronic structures of transition metal complexes of NO are controlled by the stereochemistry about the metal atom (stereochemical control of valence). The six-coordinate complex, trans-[CoNO(NCS)-(C(6)H(4) [As(CH(3))(2)](2))(2)](+), consists of [Co(III)-(N=O(-))](2+) (angle(Co-N-O) = 135°), w...
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| Veröffentlicht in: | Proc Natl Acad Sci U S A |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
National Academy of Sciences
1972
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| Online-Zugang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389815/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592038/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.69.12.3534 |
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