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Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2)

The electronic structures of transition metal complexes of NO are controlled by the stereochemistry about the metal atom (stereochemical control of valence). The six-coordinate complex, trans-[CoNO(NCS)-(C(6)H(4) [As(CH(3))(2)](2))(2)](+), consists of [Co(III)-(N=O(-))](2+) (angle(Co-N-O) = 135°), w...

Whakaahuatanga katoa

I tiakina i:
Ngā taipitopito rārangi puna kōrero
I whakaputaina i:Proc Natl Acad Sci U S A
Ngā kaituhi matua: Enemark, John H., Feltham, Robert D.
Hōputu: Artigo
Reo:Inglês
I whakaputaina: National Academy of Sciences 1972
Ngā marau:
Urunga tuihono:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389815/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592038/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.69.12.3534
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