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Stereochemical Trigger for Initiating Cooperative Interaction of the Subunits During the Oxygenation of Cobaltohemoglobin

Relative to the standard provided by an unconstrained five-coordinate imidazoleiron(II) porphyrin, the axial separation (N(ε)...P(μ)) in deoxyhemoglobin of the complexed histidine-nitrogen (N(ε)) atom from the mean plane (P(μ)) of the protoporphyrin is stretched by [unk] 0.30 Å. Retention of the sam...

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Bibliografiske detaljer
Main Authors: Hoard, J. L., Scheidt, W. R.
Format: Artigo
Sprog:Inglês
Udgivet: 1973
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC427357/
https://ncbi.nlm.nih.gov/pubmed/4521218
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