Stereochemical Control of Valence and Its Application to the Reduction of Coordinated NO and N(2)
The electronic structures of transition metal complexes of NO are controlled by the stereochemistry about the metal atom (stereochemical control of valence). The six-coordinate complex, trans-[CoNO(NCS)-(C(6)H(4) [As(CH(3))(2)](2))(2)](+), consists of [Co(III)-(N=O(-))](2+) (angle(Co-N-O) = 135°), w...
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| Publié dans: | Proc Natl Acad Sci U S A |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
National Academy of Sciences
1972
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389815/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592038/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.69.12.3534 |
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