Cargando...
Conversion of Fe-NH(2) to Fe-N(2) with release of NH(3)
Tris(phosphine)borane ligated Fe(I) centers featuring N(2)H(4), NH(3), NH(2), and OH ligands are described. Conversion of Fe-NH(2) to Fe-NH(3)(+) by addition of acid, and subsequent reductive release of NH(3) to generate Fe-N(2), is demonstrated. This sequence models the final steps of proposed Fe-m...
Gardado en:
| Main Authors: | , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2013
|
| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3565533/ https://ncbi.nlm.nih.gov/pubmed/23259776 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307714m |
| Tags: |
Engadir etiqueta
Sen Etiquetas, Sexa o primeiro en etiquetar este rexistro!
|