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Conversion of Fe-NH(2) to Fe-N(2) with release of NH(3)
Tris(phosphine)borane ligated Fe(I) centers featuring N(2)H(4), NH(3), NH(2), and OH ligands are described. Conversion of Fe-NH(2) to Fe-NH(3)(+) by addition of acid, and subsequent reductive release of NH(3) to generate Fe-N(2), is demonstrated. This sequence models the final steps of proposed Fe-m...
Gorde:
| Egile Nagusiak: | , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2013
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3565533/ https://ncbi.nlm.nih.gov/pubmed/23259776 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307714m |
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